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https://hdl.handle.net/1822/7840
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Campo DC | Valor | Idioma |
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dc.contributor.author | Fonseca, A. Maurício C. | - |
dc.contributor.author | Raposo, M. Manuela M. | - |
dc.contributor.author | Sousa, Ana M. R. C. | - |
dc.contributor.author | Kirsch, G. | - |
dc.contributor.author | Beley, Marc | - |
dc.date.accessioned | 2008-05-21T15:28:40Z | - |
dc.date.available | 2008-05-21T15:28:40Z | - |
dc.date.issued | 2005 | - |
dc.date.submitted | 2005 | - |
dc.identifier.citation | "European Journal of Inorganic Chemistry". ISSN 1434-1948. 21(2005) 4361-4365. | eng |
dc.identifier.issn | 1434-1948 | eng |
dc.identifier.uri | https://hdl.handle.net/1822/7840 | - |
dc.description.abstract | Trans-[FMo{NN=CH(5´-R-thienyl)}(dppe)2][BF4] (R = OMe and OEt) and trans[FMo{NN=CH(5’-R-2,2’-bithienyl)}(dppe)2][BF4] (R = OMe, OEt and O(iPr)) were synthesised in good yields by reacting 2-formyl-5-alkoxylthiophenes and 5-formyl-5’-alkoxy-2,2-’bithiophenes respectively, with hydrazido(2-) complex, trans-[MoF(NNH2)(dppe)2][BF4]. The electrochemical, spectroscopic and solvatochromic properties of these compounds were studied. These results suggest that efficient π conjugated systems were obtained due to the low energy charge transfer between the metal and the heterocyclic moieties. | eng |
dc.description.sponsorship | Fundação para a Ciência e a Tecnologia (FCT) | eng |
dc.language.iso | eng | eng |
dc.publisher | Wiley-VCH Verlag | eng |
dc.rights | openAccess | eng |
dc.subject | 2-formyl-5-alkoxylthiophenes | eng |
dc.subject | 5-formyl-5’-alkoxy-2,2’-bithiophenes | eng |
dc.subject | Sulfur heterocycles | eng |
dc.subject | Molybdenum complexes | eng |
dc.subject | Hydrazido(-2) | eng |
dc.subject | Conjugated systems | eng |
dc.subject | UV-Visible spectroscopy | eng |
dc.subject | Solvatochromism | eng |
dc.subject | Electrochemistry | eng |
dc.subject | Redox properties | eng |
dc.subject | Nonlinear optical (NLO) materials | eng |
dc.subject | molybdenum | por |
dc.subject | N ligands | por |
dc.title | Synthesis, electrochemical and spectroscopic properties of molybdenum complexes bearing 5-alkoxy-thiophenic or- bithiophenic groups | eng |
dc.type | article | por |
dc.peerreviewed | yes | eng |
sdum.pagination | 4361–4365 | eng |
sdum.publicationstatus | published | eng |
sdum.volume | 21 | eng |
oaire.citationStartPage | 4361 | por |
oaire.citationEndPage | 4365 | por |
oaire.citationIssue | 21 | por |
dc.identifier.doi | 10.1002/ejic.200401012 | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | European Journal of Inorganic Chemistry | por |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Manuscript-ejic.pdf | Documento principal | 112,53 kB | Adobe PDF | Ver/Abrir |