Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/63454
Registo completo
Campo DC | Valor | Idioma |
---|---|---|
dc.contributor.author | Teixeira, Paulo Francisco | por |
dc.contributor.author | Sutera, F. | por |
dc.contributor.author | Scaffaro, R. | por |
dc.contributor.author | Covas, J. A. | por |
dc.contributor.author | Hilliou, L. | por |
dc.date.accessioned | 2020-01-28T18:48:26Z | - |
dc.date.issued | 2019 | - |
dc.identifier.issn | 1788-618X | por |
dc.identifier.uri | https://hdl.handle.net/1822/63454 | - |
dc.description.abstract | The time evolution of organoclay particle size and volume fraction, as well as the shear viscosity, are measured in-line for a series of Poly(lactic acid)/organoclay composites, using a rheo-optical die coupled to a prototype modular co-rotating twin screw extruder. The small angle light scattering patterns and light attenuation recorded during transient experiments indicate that clay dispersion develops through melt intercalation between the clay galleries, thereby expanding the aggregates size, and eventually leads to aggregates break-up, i.e., exfoliation. The simultaneous recording of shear viscosity also indicates that smaller viscosities promote a faster melt intercalation and exfoliation but hinder the extent of clay dispersion. The methodology used in the present study validates the well accepted mechanism for clay dispersion and can be applied straight away for the monitoring of PNC manufacturing during practical production. | por |
dc.description.sponsorship | This work is supported by National Funds through FCT Portuguese Foundation for Science and Technology, Reference UID/CTM/50025/2013 and FEDER funds through the COMPETE 2020 Programme under the project number POCI-01-0145-FEDER-007688. LH acknowledges funding from the FCT Investigator Programme through grant IF/00606/2014. | por |
dc.language.iso | eng | por |
dc.publisher | Budapest University of Technology | por |
dc.relation | info:eu-repo/grantAgreement/FCT/5876/147333/PT | por |
dc.rights | restrictedAccess | por |
dc.subject | nanocomposites | por |
dc.subject | industrial applications | por |
dc.subject | extrusion | por |
dc.subject | exfoliation | por |
dc.subject | in-process monitoring | por |
dc.title | Multi-parameter in-process monitoring of clay dispersion during melt compounding with PLA | por |
dc.type | article | - |
dc.peerreviewed | yes | por |
oaire.citationStartPage | 276 | por |
oaire.citationEndPage | 285 | por |
oaire.citationIssue | 3 | por |
oaire.citationVolume | 13 | por |
dc.date.updated | 2020-01-28T17:54:36Z | - |
dc.identifier.doi | 10.3144/expresspolymlett.2019.23 | por |
dc.date.embargo | 10000-01-01 | - |
dc.subject.wos | Science & Technology | - |
sdum.export.identifier | 5561 | - |
sdum.journal | eXPRESS Polymer Letters | por |
Aparece nas coleções: | IPC - Artigos em revistas científicas internacionais com arbitragem |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
EPL 2019 pla with nanoclay inline expts.pdf Acesso restrito! | 571,5 kB | Adobe PDF | Ver/Abrir |