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dc.contributor.authorGonçalves, Raquel C. R.por
dc.contributor.authorNogueira, Mariana B.por
dc.contributor.authorCosta, Susana P. G.por
dc.contributor.authorRaposo, M. Manuela M.por
dc.date.accessioned2018-12-05T13:39:55Z-
dc.date.available2018-12-05T13:39:55Z-
dc.date.issued2018-11-14-
dc.date.submitted2018-
dc.identifier.citationGonçalves, R.; Nogueira, M.; Costa, S. P. G.; Raposo, M. M. M.; BODIPY derivatives: synthesis and evaluation of their optical properties. Proceedings of the 22nd International Electronic Conference on Synthetic Organic Chemistry 1 a 30 de novembro de 2018, Sciforum Electronic Conferences Series, doi: 10.3390/ecsoc-22-05700.por
dc.identifier.urihttps://hdl.handle.net/1822/57137-
dc.description.abstractThree BODIPY derivatives functionalized at meso and 2 position were synthesized in 22-59% yield. The compounds were characterized by the usual spectroscopic techniques and a photophysical study was also undertaken. The BODIPY derivatives presented absorption bands in the 494-512 nm range and were also emissive with fluorescence bands in the 512-514 nm interval. A preliminary study on the sensing ability of BODIPY functionalized at position 2 with a benzimidazole was carried out in acetonitrile and acetonitrile/water (75:25) solutions in the presence of anions and cations with environmental, biomedical and analytical relevance. A highly selective response was obtained for Hg2+ and Fe3+ in acetonitrile/water solution.por
dc.description.sponsorshipThank are due to Fundação para a Ciência e Tecnologia (Portugal) and FEDER-COMPETE for financial support through Centro de Química (UID/ QUI/0686/2016). The NMR spectrometer Bruker Avance III 400 is part of the National NMR Network and was purchased within the framework of the National Program for Scientific Re-equipment, contract REDE/1517/RMN/2005 with funds from POCI 2010 (FEDER) and FCT.por
dc.language.isoengpor
dc.publisherMDPIpor
dc.rightsopenAccesspor
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/por
dc.subjectSynthesispor
dc.subjectLabellingpor
dc.subjectBODIPYpor
dc.subjectProbepor
dc.subjectOptical Chemosensorspor
dc.subjectFluorescencepor
dc.subjectHeterocyclepor
dc.subjectPyrrolepor
dc.subjectAldehydepor
dc.subjectBenzimidazolepor
dc.subjectFe3+por
dc.subjectHg2+por
dc.titleBODIPY derivatives: synthesis and evaluation of their optical propertiespor
dc.typeconferencePaperpor
dc.peerreviewedyespor
dc.relation.publisherversionhttps://sciforum.net/manuscripts/5700/manuscript.pdfpor
oaire.citationConferenceDate15 nov. - 15 dec. 2018por
sdum.event.title22nd International Electronic Conference on Synthetic Organic Chemistry (ECSOC 2018)por
sdum.event.typeconferencepor
dc.identifier.doi10.3390/ecsoc-22-05700por
dc.subject.fosCiências Naturais::Ciências Químicaspor
dc.description.publicationversioninfo:eu-repo/semantics/publishedVersionpor
sdum.conferencePublicationProceedings of the 22nd International Electronic Conference on Synthetic Organic Chemistrypor
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