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https://hdl.handle.net/1822/5613
Título: | NMR structural elucidation of the arabinan from Prunus dulcis immunobiological active pectic polysaccharides |
Autor(es): | Dourado, Fernando Cardoso, Susana M. Silva, Artur M. S. Gama, F. M. Coimbra, Manuel A. |
Palavras-chave: | Arabinan Prunus dulcis Almond NMR Structure |
Data: | Out-2006 |
Editora: | Elsevier 1 |
Revista: | Carbohydrate polymers |
Citação: | "Carbohydrate polymers". ISSN 0144-8617. 66:1 (Oct. 2006) 27-33. |
Resumo(s): | The structure of the arabinan moiety of a purified arabinan-rich pectic polysaccharide from the cell walls of Prunus dulcis seeds was investigated by NMR spectroscopy. This polymer, which is able to induce a lymphocyte stimulatory effect, had an arabinan glycosidiclinkage composed of T-Araf: (1→5)-Araf: (1→3,5)-Araf: (1→2,3,5)-Araf in the relative proportions of approximately 3:2:1:1. Based on the ¹H, ¹³C, COSYPR, gHSQC and gHMBC spectra of analysed arabinan, a tentative structure is presented, showing that it is composed by a very branched and, possibly, repetitive structure of seven residues. The observed (1→5) direct linkage between (1→2,3,5)- Araf and (1→3,5)-Araf residues support the occurrence of these contiguous branched residues in the arabinan backbone. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/5613 |
DOI: | 10.1016/j.carbpol.2006.02.020 |
ISSN: | 0144-8617 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CEB - Publicações em Revistas/Séries Internacionais / Publications in International Journals/Series |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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CarbhydratePolym2006-Dourado[1].pdf | 299,46 kB | Adobe PDF | Ver/Abrir |