Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/49070
Registo completo
Campo DC | Valor | Idioma |
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dc.contributor.author | Esteves, Cátia Isabel Canavezes | por |
dc.contributor.author | Raposo, M. Manuela M. | por |
dc.contributor.author | Costa, Susana P. G. | por |
dc.date.accessioned | 2018-01-08T11:51:08Z | - |
dc.date.available | 2018-01-08T11:51:08Z | - |
dc.date.issued | 2016-07 | - |
dc.identifier.citation | Dyes and Pigments, 2016, 134, 258-268 | por |
dc.identifier.issn | 0143-7208 | por |
dc.identifier.uri | https://hdl.handle.net/1822/49070 | - |
dc.description.abstract | Novel fluorescent 4,5-diarylimidazolyl-phenylalanines 3a-d were prepared by reaction of N-tert-butyloxycarbonyl-4-formylphenylalanine methyl ester and appropriate (hetero)aromatic diones. The photophysical properties of these new unnatural amino acids were evaluated by UV-Vis absorption and fluorescence spectroscopy in solvents of different character and aqueous mixtures with acetonitrile. They were evaluated as novel amino acid based fluorimetric chemosensors for ions through spectrophotometric and spectrofluorimetric titrations with biologically and analytically important anions and cations such as F-, OH-, Cu2+ and Fe3+. The results indicate that there was a strong interaction through the donor N, O and S atoms at the side chain, especially for 4,5-di(furan-2’-yl)imidazolyl-phenylalanine 3a and 4,5-di(thiophen-2’-yl)imidazolyl-phenylalanine 3b with Cu2+ and Fe3+, in a 1:1 complex stoichiometry. The photophysical and metal ion sensing properties of these amino acids suggest that they can be suitable for incorporation into chemosensory peptidic frameworks. | por |
dc.description.sponsorship | Thanks are due to Fundação para a Ciência e Tecnologia (FCT-Portugal) and FEDER-COMPETE for financial support through Centro de Química [PEst-C/QUI/UI0686/2011 (F-COMP-01-0124-FEDER-022716)] and a PhD grant to C.I.C. Esteves (SFRH/BD/68360/2010). The NMR spectrometer Bruker Avance III 400 is part of the National NMR Network and was purchased with funds from FCT and FEDER. | por |
dc.language.iso | eng | por |
dc.publisher | Elsevier 1 | por |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F68360%2F2010/PT | por |
dc.rights | openAccess | por |
dc.subject | 2,4,5-triarylimidazoles | por |
dc.subject | Phenylalanine | por |
dc.subject | Unnatural amino acids | por |
dc.subject | Chemosensors | por |
dc.subject | Fluorescence | por |
dc.title | New 2,4,5-triarylimidazoles based on a phenylalanine core: synthesis, photophysical characterization and evaluation as fluorimetric chemosensors for ion recognition | por |
dc.type | article | por |
dc.peerreviewed | yes | por |
dc.relation.publisherversion | https://doi.org/10.1016/j.dyepig.2016.07.020 | por |
oaire.citationStartPage | 258 | por |
oaire.citationEndPage | 268 | por |
oaire.citationVolume | 134 | por |
dc.identifier.eissn | 1873-3743 | por |
dc.identifier.doi | 10.1016/j.dyepig.2016.07.020 | por |
dc.subject.fos | Ciências Naturais::Ciências Químicas | por |
dc.description.publicationversion | info:eu-repo/semantics/publishedVersion | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | Dyes and Pigments | por |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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artigo Esteves DYPI 2016.pdf | 1,96 MB | Adobe PDF | Ver/Abrir |