Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/44394
Título: | Spectroscopic characterization of novel push-pull thieno[3,2-b]thiophene derivatives functionalized with different acceptor groups. |
Autor(es): | Fernandes, Sara Sofia Marques Raposo, M. Manuela M. |
Palavras-chave: | Push-pull pi-conjugated systems UV-Visible Fluorescence DSSC NLO Thienothiophene |
Data: | Jun-2016 |
Resumo(s): | Push-pull π-conjugated systems of the thiophene type have several interesting applications as nonlinear optical (NLO) and photochromic materials, sensitizers for dye sensitized solar cells (DSSCs), etc. As part of an on-going research to develop efficient donor-acceptor substituted heterocyclic systems for diverse applications such as NLO and organic sensitizers for DSSCs, we report in this communication the synthesis and characterization of two novel heterocyclic compounds 1-2, using several synthetic methodologies. These new push-pull systems are based on a furan donor moiety and a thieno[3,2-b]thiophene spacer, functionalized with different electron withdrawing groups. The full characterization of the new compounds was performed using UV-visible (absorption and emission), 1H NMR and IR spectroscopies. The experimental results showed that the optical and electronic properties of these push-pull systems can be readily tuned by varying the electron-acceptor strength of the groups linked to the thieno[3,2-b]thiophene π-bridge. Moreover, their push-pull character with a significant intramolecular charge transfer (ICT) from the donor furan heterocycle to the acceptor groups and a high polarizability of the whole π-conjugated systems reveal their potential application as chromophores for NLO and/or as sensitizers for DSSCs. |
Tipo: | Comunicação em painel |
URI: | https://hdl.handle.net/1822/44394 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Comunicações e Proceedings |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Abstract ETCAQ 2016.pdf | 235,99 kB | Adobe PDF | Ver/Abrir |