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https://hdl.handle.net/1822/43555
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Campo DC | Valor | Idioma |
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dc.contributor.author | Oliveira, F. | por |
dc.contributor.author | Dencheva, Nadya Vasileva | por |
dc.contributor.author | Martins, P. | por |
dc.contributor.author | Lanceros-Méndez, S. | por |
dc.contributor.author | Denchev, Z. | por |
dc.date.accessioned | 2016-12-20T10:11:58Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | Oliveira, F., Dencheva, N., Martins, P., Lanceros-Mendez, S., & Denchev, Z. (2016). Reactive microencapsulation of carbon allotropes in polyamide shell-core structures and their transformation in hybrid composites with tailored electrical properties. Express Polymer Letters, 10(2), 160-175. doi: 10.3144/expresspolymlett.2016.15 | por |
dc.identifier.issn | 1788-618X | - |
dc.identifier.uri | https://hdl.handle.net/1822/43555 | - |
dc.description.abstract | Polyamide 6 microcapsules (PAMC) loaded with 2-10 wt% of different carbon allotropes: carbon black, multi-walled carbon nanotubes, carbon nanofibers and graphite were synthesized via activated anionic polymerization (AAROP) of ε-caprolactam in solution performed in the presence of the respective micro- or nanosized loads. The forming high-molecular weight microporous PAMC showed typical diameters of 15-35 μm, the filler particles being entrapped in the core, as proven by microscopy methods. The melt processing of the loaded microcapsules produced PA6/C-filler hybrid thermoplastic composites with homogeneous distribution of one or two C-fillers even at loads of ca. 10 % without any functionalization. The crystalline structure of all PAMC and molded composites was studied by thermal (DSC, TGA) and X-ray diffraction methods focusing on eventual modifications during the transition from PAMC to molded plates. Mechanical tests in tension and electrical conductivity measurements showed that transforming loaded PAMC into composites by melt processing could be a facile and rapid method to fabricate polyamide composites with improved mechanical performance and tailored electrical and dielectric properties. | por |
dc.description.sponsorship | The authors gratefully acknowledge the financial support of the Portuguese Foundation for Science and Technology (FCT) in the frames of the Strategic Project LA25/2013-2014 and post-doctoral grant SFRH/BPD/45252 co-financed by QREN-POPH program of the EU and of MiNaXS beamline of DESY – Hamburg, Germany. This work was also supported by FEDER through the COMPETE Program and by the FCT in the framework of the Strategic Project PEST-C/FIS/UI607/2013. P. Martins thanks the FCT for the SFRH/BPD/96227/2013 grant. | por |
dc.language.iso | eng | por |
dc.publisher | BME-PT and GTE | - |
dc.relation | LA25/2013-2014 | por |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F45252%2F2008/PT | por |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132974/PT | por |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F96227%2F2013/PT | por |
dc.rights | restrictedAccess | por |
dc.subject | Activated anionic polymerization | por |
dc.subject | Polymer synthesis | por |
dc.subject | Microcapsules | por |
dc.subject | Tailor-made polymers | por |
dc.subject | Polymer composites | por |
dc.subject | carbon allotropes | por |
dc.title | Reactive microencapsulation of carbon allotropes in polyamide shell-core structures and their transformation in hybrid composites with tailored electrical properties | por |
dc.type | article | por |
dc.peerreviewed | yes | por |
sdum.publicationstatus | info:eu-repo/semantics/publishedVersion | por |
oaire.citationStartPage | 160 | por |
oaire.citationEndPage | 175 | por |
oaire.citationIssue | 2 | por |
oaire.citationTitle | Express Polymer Letters | por |
oaire.citationVolume | 10 | por |
dc.identifier.doi | 10.3144/expresspolymlett.2016.15 | por |
dc.subject.fos | Ciências Naturais::Ciências Físicas | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | eXPRESS Polymer Letters | por |
Aparece nas coleções: | CDF - FCD - Artigos/Papers (with refereeing) |
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result 48.pdf Acesso restrito! | 2,07 MB | Adobe PDF | Ver/Abrir |