Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/4025
Registo completo
Campo DC | Valor | Idioma |
---|---|---|
dc.contributor.author | Viciosa, M. T. | - |
dc.contributor.author | Dionísio, M. | - |
dc.contributor.author | Silva, R. M. | - |
dc.contributor.author | Reis, R. L. | - |
dc.contributor.author | Mano, J. F. | - |
dc.date.accessioned | 2006-01-18T17:16:27Z | - |
dc.date.available | 2006-01-18T17:16:27Z | - |
dc.date.issued | 2004 | - |
dc.identifier.citation | "Biomacromolecules". ISSN 1525-4497. 5:5 (Sept. 2004) 2073-2078. | eng |
dc.identifier.issn | 1525-4497 | - |
dc.identifier.uri | https://hdl.handle.net/1822/4025 | - |
dc.description.abstract | Neutralized and nonneutralized chitosan films subject to different thermal treatments were studied by dielectric relaxation spectroscopy from -130 to +150 °C in the frequency range between 20 Hz and 1 MHz. Two main relaxation processes, both arrhenian type, were detected: process I at temperatures below 0 °C with a mean activation energy of 49 ( 1 kJ mol-1, which has the characteristics of a secondary relaxation process related with local chain dynamics, and process II observable at higher temperatures with an activation energy of 94 ( 2 kJ mol-1, correlated with dc conductivity, which is found in dried polysaccharides systems. Process I is always observed in neutralized chitosan, but it is strongly depleted in the wet nonneutralized form. Although the location of process I is independent of NH2/NH3 + side group, process II deviates to higher temperatures with dryness in both chitosan forms, being located at lower temperatures in nonneutralized chitosan. | eng |
dc.description.sponsorship | FCT, Foundation for Science and Technology, through the POCTI (POCTI/CTM/47363/2002) and FEDER programs. | por |
dc.language.iso | eng | eng |
dc.publisher | ACS Publications | eng |
dc.rights | openAccess | eng |
dc.title | Molecular motions in chitosan studied by dielectric Relaxation spectroscopy | eng |
dc.type | article | eng |
dc.peerreviewed | yes | eng |
oaire.citationStartPage | 2073 | por |
oaire.citationEndPage | 2078 | por |
oaire.citationIssue | 5 | por |
oaire.citationVolume | 5 | por |
dc.identifier.doi | 10.1021/bm049685b | por |
dc.identifier.pmid | 15360326 | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | Biomacromolecules | por |
Aparece nas coleções: | 3B’s - Artigos em revistas/Papers in scientific journals |