Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/32137
Título: | Synthesis and photophysical characterization of novel triphenylamine-benzimidazole derivatives |
Autor(es): | Batista, Rosa Maria Ferreira Pina, J. Melo, J. Seixas de Costa, Susana P. G. Raposo, M. Manuela M. |
Palavras-chave: | Synthesis Fluorescence Ttriphenylamine Benzimidazole Triplet-triplet absorption spectra UV-visible spectroscopy Thermal stability OLEDs High fluorescence quantum yields |
Data: | 2013 |
Editora: | Sociedade Portuguesa de Química (SPQ) |
Resumo(s): | Research on organic luminescent materials has been intensely pursued due to their importance in technological applications related to signaling, fluorescent biosensory/chemosensory materials, molecular switches and organic light emitting diodes (OLEDs). Organic fluorophores such as triphenylamine and benzimidazole derivatives have attracted a particular attention owing to their high emission efficiency being widely used as electron transporters and emitting layers for OLEDs.1 Recently, we have been investigating the potential of heterocyclic systems bearing functionalized (benz)imidazole derivatives exhibiting high thermal stability, interesting emissive and chemosensory properties.2 In this communication we report the synthesis and photophysical characterization of triphenylamine-benzimidazoles (compounds 1a-d) which were synthesized by a one step reaction through the Na2S2O4 reduction of several commercially available o-nitroanilines in the presence of triphenylamine aldehyde in DMSO at 120 °C. Compounds 1a-d bear different functionalization at position 5 of the benzimidazole with electron-donor or acceptor groups (Figure 1). A comprehensive spectral and photophysical investigation of these compounds including absorption, fluorescence and triplet-triplet absorption spectra, together with quantum yields of fluorescence, internal conversion, intersystem crossing and singlet oxygen and rate constants for the radiative and radiationless processes has been undertaken in solution at room temperature. It is shown that compounds 1a-d exhibit high fluorescence quantum yields (0.70-0.78). Additionally, a comparison between the optical and photophysical properties of 1a-d will be also presented and discussed. |
Tipo: | Resumo em ata de conferência |
URI: | https://hdl.handle.net/1822/32137 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Comunicações e Proceedings |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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SPQ 2013 .pdf | Documento principal | 156,41 kB | Adobe PDF | Ver/Abrir |