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https://hdl.handle.net/1822/32119
Título: | Nonlinear optical materials formed by push-pull (bi)thiophene derivatives functionalized with di(tri)cyanovinyl acceptor groups |
Autor(es): | Wojciechowski, A. Raposo, M. Manuela M. Castro, M. Cidália R. Kuznik, W. Janczrek, I. Fuks Bureš, F. Kityk, I. V. |
Palavras-chave: | Synthesis Bithiophene Nonlinear optical (NLO) materials Polymethylmethacrylate (PMMA) matrices UV-visible spectroscopy DFT studies Second order susceptibilities Push-pull conjugated heterocyclic systems Di(tri)cyanovinyl acceptor groups PMMA Structure-property relationships |
Data: | 2014 |
Editora: | Springer |
Revista: | Journal of Materials Science: Materials in Electronics |
Resumo(s): | Studies of the second-order nonlinear optical susceptibilities of six NLOphores bearing di(tri)cyanovinyl acceptor groups linked to (bi)thiophene heterocyclic donor systems were performed for the first time in polymethyl methacrylate (PMMA) matrices with a 1064 nm laser working in the 20 ns time pulse regime. Absorption spectra and DFT calculations were also performed. This multidisciplinary study showed that modulation of the optical (linear and nonlinear) properties can be achieved by increasing the length of the -conjugated heterocyclic system (thiophene vs. bithiophene), the strength of the electron donor groups (HMeO/EtOEt2N) as well as the strength of the electron acceptor moieties (DCV vs. TCV, two vs. three electron withdrawing cyano groups). Due to the relatively high second-order susceptibilities (0.08 to 6.45 pm/V), the studied push-pull chromophores can be denote as very potent NLOphores. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/32119 |
DOI: | 10.1007/s10854-014-1793-6 |
ISSN: | 0957-4522 1573-482X |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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J. Mater. Sci. Mater. Electron. 2014.pdf | Documento principal | 512,16 kB | Adobe PDF | Ver/Abrir |