Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/31916
Título: | Amino acids based on 2,4,5-triarylimidazoles: synthesis and evaluation as new chemosensors for ion recognition |
Autor(es): | Esteves, Cátia I. C. Raposo, M. Manuela M. Costa, Susana P. G. |
Palavras-chave: | 2,4,5-triarylimidazoles Unnatural amino acids Chemosensors Fluorescence |
Data: | 2013 |
Editora: | MDPI |
Resumo(s): | N-tert-butyloxycarbonyl-4-formylphenylalanine methyl ester and appropriate heterocyclic diones were used in the synthesis of novel fluorescent unnatural amino acids, namely 2,4,5-triarylimidazolyl-alanines. These new compounds were fully characterised by the usual spectroscopic techniques, such as IR and NMR. The photophysical properties of the amino acids were evaluated by UV-Vis absorption and fluorescence spectroscopy in solvents of different character. Interaction studies with biologically and analytically important ions such as F-, OH-, Cu2+ and Fe3+, through spectrophotometric and spectrofluorimetric titrations were carried out to assess their potential as chemosensors. |
Tipo: | Artigo em ata de conferência |
Descrição: | Sciforum Electronic Conference Series, Vol. 17, 2013, b015 |
URI: | https://hdl.handle.net/1822/31916 |
DOI: | 10.3390/ecsoc-17-b015 |
Versão da editora: | http://www.sciforum.net/conference/ecsoc-17/paper/2269 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Comunicações e Proceedings |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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ecsoc-17_2269_manuscript.pdf | 553,96 kB | Adobe PDF | Ver/Abrir |