Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/31835
Título: | Naphtyl-imidazo-anthraquinones as novel colorimetric and fluorimetric chemosensors for ion sensing |
Autor(es): | Batista, Rosa M. F. Costa, Susana P. G. Raposo, M. Manuela M. |
Palavras-chave: | Imidazole Anthraquinone Colorimetric and fluorimetric chemosensors Fluoride Cyanide Aqueous media Naked-eye detection Fluoride, Cyanide |
Data: | Mai-2013 |
Editora: | Elsevier 1 |
Revista: | Journal of Photochemistry and Photobiology A: Chemistry |
Citação: | R.M.F. Batista et al., Journal of Photochemistry and Photobiology A: Chemistry 259 (2013) 33–40 |
Resumo(s): | Novel colorimetric and fluorimetric chemosensors for F− and CN− containing anthraquinone and imidazole as signalling/binding sites have been synthesised and characterised. Upon addition of F−, CN− and OH− to acetonitrile solutions of compounds 1-2, a marked colour change from yellow to pink was observed and the fluorescence emission of 1 was switched “on”, whereas for 2 there was a fluorescence quenching. Considering recognition in organic aqueous mixture, it was found that selectivity for CN- was achieved for both receptors, with an easily detectable colour change from yellow to orange. Compounds 1-2 in their deprotonated form, after fluoride addition, were studied as metal ion chemosensors and displayed a drastic change from pink to yellow after metal ion complexation giving a yellow-pink-yellow, reversible colorimetric reaction and a “on-off-on” fluorescence in acetonitrile. The binding stoichiometry between the receptors and the anions and cations was found to be 1:1 and 2:1 respectively. The binding process was also followed by 1H NMR titrations which corroborated the previous findings. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/31835 |
DOI: | 10.1016/j.jphotochem.2013.03.001 |
ISSN: | 1010-6030 |
Versão da editora: | http://www.sciencedirect.com/science/article/pii/S1010603013000890 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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manuscript JPPA 2013.pdf | 4,58 MB | Adobe PDF | Ver/Abrir |